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1 B This answer describes a metallic solid 2 C This answer describes an ionic solid 3 A This answer describes a covalent network solid 4 D This answers describes a solid consisting of discrete polar molecules 5 D Each of the carbon atoms is covalently bonded to four other carbon atoms 6 E Sulfur dioxide molecules are polar 7 A Hydrogen bonding occurs when hydrogen is directly bonded to F, O, and in this case N 8 A This is the definition of the critical point 9 B The gas liquid line always has a positive slope B negates C The triple point is below the freezing point The triple point may be above or below 1 atm 10 A Argon is a noble gas; none of the bonding choices are options 11 B Diamond is a covalent network solid with a large number of strong covalent bonds between the carbon atoms 12 B The bottom of the liquid region on the phase diagram is the triple point 13 D The size of the container is irrelevant Sealing the container will cause an increase in pressure that will increase the boiling point A decrease in pressure will lower the boiling point 14 E The compound with the higher surface tension is the one with the stronger intermolecular force The hydrogen bonding in 1-butanol is stronger than the dipole dipole attractions in diethyl ether 15 A The sequence for these similar molecules is nonpolar, then one hydrogen bond, then two hydrogen bonds 16 A This change is condensation, so the energy is the heat of condensation 17 C The only applicable factor listed is the charge difference The chloride ion is larger than the fluoride ion The ion ratio is not important 18 E The point must be on the line separating the solid from the liquid phase 19 D The solid begins to melt at A, and finishes melting at B.

A meeting is only a means of communication Its purpose should be to produce a change in procedure This procedure could be in knowledge, attitude, behavior, or skill In our meetings, management gives information, it collects information, it pools information, and it discusses the best way to approach the problem We have one hard and fast rule: Once the group is agreed upon the method, there is no deviation until the group agrees to the change

Solution for n yields:

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Alternatively, where b = m/ k , and k is Henry's constant Note that when P + 0, n / P properly approaches k At the other extreme, where P -+ oo, n approaches m , the saturation value of the specific amount absorbed, representing full monolayer coverage Based on the same assumptions as for the ideal-lattice-gas equation, Langmuir in 1918 derived Eq (14106) by noting that at equilibrium the rate of adsorption and the rate of desorption of gas molecules must be the same23For monolayer adsorption, the number of sites may be divided into the fraction occupied 0 and the fraction vacant 1 - 0 By definition,

n rn- n and 1-0=rn rn where m is the value of n for full monolayer coverage For the assumed conditions, the rate of adsorption is proportional to the rate at which molecules strike the surface, which in turn is proportional to both the pressure and the fraction 1 - 0 of unoccupied surface sites The rate of desorption is proportional to the occupied fraction 0 of sites Equating the two rates gives:

Answer the following questions You have 10 minutes You may not use a calculator You may use the tables at the back of the book

In other words, no second-guessing and no backbiting, a policy that fostered solidarity and loyalty among his assistants He further earned the loyalty of those assistants by paying them well and using their time wisely And, of course, everybody loved being associated with a winner In the years that he served the Packers as coach and general manager, he limited his outside activities mainly to the occasional product endorsement and speaking engagement (The number of opportunities to do both, of course, went up sharply as the Packers crept into the national consciousness as winners) At first, he spoke primarily to local groups, but as he became a national figure, he spoke to groups across the country At first, he favored gatherings at which he felt some natural kinship with the people such as Catholic charitable events but over time he accepted more offers to speak to organizations like the National Association of Manufacturers (NAM) and other industry groups His themes remained consistent, even as his platform got bigger The advice he gave to the fund-raisers at St Elizabeth s Hospital in Appleton, Wisconsin, in 1962 could have been replayed years later at the NAM convention:

1 3 -

"See, eg, T L Hill, An Introduction to Statistical Mechanics, sec 7-1, Addison-Wesley, Reading, MA, 1960 221rving Langmuir (1881-1957), the second American to receive the Nobel Prize in chemistry, awarded for his contributions in the field of surface chemistry 231Langmuir, J Am Chem Soc, vol 40, p 1361, 1918

where K and K' are proportionality (rate) constants Solving for n and rearranging yields:

In order to succeed, this group will need a singleness of purpose, they will need a dedication,

The above figure shows a typical phase diagram for a one-component system Use this diagram to answer the following questions

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